Unlike its console counterparts, Mob Wars does not feature free-roaming environments. Instead, the game is restricted to a series of story missions involving Aldo Trapani. However, Mob Wars includes a new turn-based strategy mode with the aim of controlling all of New York City by neutralizing the rival families, completed by issuing orders and executing them as real-time missions. The portable version of the game also lacks driving sections, even in the story missions, where driving segments are replaced with cutscenes.
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The files is zip. So you must extract that zip first, and you will get iso files for that game. Then you must put that iso files to your PSP game directory.
To use this PSP ROM on your Android device you need to download and install the emulator first:
PPSSPP Gold - PSP Emulator For Android - Platinmods.com - Android & iOS MODs, Mobile Games & Apps